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(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine CAS 135616-40-9
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Product name:
(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Brand:
Entrepreneur
Cas No.:
135616-40-9
Purity:
98% min
Boiling point:
615.2 °C at 760 mmHg
Flash point:
421.6 °C
Melting point::
205-207 °C
Country of Origin:
China
Appearance:
Yellow Powder
Delivery Time:
Within 3-10 working days according to the quantity
Other names:
(R,R)-Jacobsen's ligand
(R,R)-JACOBSEN LIGAND
MFCD00191800
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Features

 Chirality: (R,R)-Jacobsen's ligand is chiral, meaning it has a non-superimposable mirror image. This property allows it to induce chirality in metal-catalyzed reactions, leading to the formation of enantiomerically enriched products.

❷ Asymmetric Induction: The ligand demonstrates excellent enantioselectivity in various asymmetric reactions. It can direct the reaction to produce one specific enantiomer of a chiral product with high selectivity, making it a valuable tool in asymmetric synthesis.

 Versatility: (R,R)-Jacobsen's ligand is widely applicable in a range of asymmetric transformations, including epoxidation, cyclopropanation, and aminohydroxylation of alkenes. Its versatility enables the synthesis of diverse chiral compounds with various functionalities.

❹ Catalytic Efficiency: The ligand acts as a catalyst in the reactions, and only a small amount is required to achieve significant enantioselectivity. This catalytic efficiency makes it cost-effective and environmentally friendly.

❺ High Yield: The use of (R,R)-Jacobsen's ligand often results in high yields of the desired chiral products, ensuring efficient and practical synthetic processes.

❻ Steric and Electronic Control: The unique structure of the ligand provides both steric and electronic control over the reaction, influencing the selectivity of the reaction and promoting the formation of specific enantiomers.

❼ Synthetic Advantages: (R,R)-Jacobsen's ligand allows chemists to access enantiomerically enriched compounds in a more straightforward and efficient manner than traditional resolution methods.

Applications

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Specifications

Product Name(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Cas No.135616-40-9
Molecular FormulaC36H54N2O2
Molecular Weight 546.84
Appearance Yellow powder
Purity98% Min
Boiling point615.2 °C at 760 mmHg
Melting point205-207 °C(lit.)
Flash point421.6°C
Refractive index1.547


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Storage

Keep container tightly closed. Take care to store in a cool and dark place, away from incompatibles.

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